超原子是一个表现出元素的原子性质的原子团簇。Y代表一个主族或过渡金属原子,LiF2, (Li3)+(SH)-(SH=LiF2,钠原子从蒸汽冷却时自然凝结成团簇时优先含有原子个数为(2,CN,N, 金配体金属团簇超原子 RS(AuSR)2 Aun(SR)n−1 Aun(SR)n+1 Aum(S)n - Aum(SR)n+ Au25–nAgn(SH)1818- (n = 1, 2, 4, 6, 8, 10, 12) Au25(SMe)18− Au25(SR)18− XAu24(SR)18 (X=Mn,C,Cd) Au24(SR)20 Au102(p-MBA)44 Au102(SR)44 Au144(SR)60 其它配体金属团簇超原子 Ga23(N(Si(CH3)3)2)11 Al50(C5(CH3)5)12 参看 玻色–爱因斯坦凝聚 参考 外部链接 Designer Magnetic Superatoms , J.U. Reveles, et al. 2009 Gold Superatom Complexes , M. Walter et al. 2008 Gold Superatom Complexes P.D. Jadzinsky et al. 2007 Multiple Valence Superatoms , J.U. Reveles, S.N. Khanna, P.J. Roach, and A.W. Castleman Jr., 2006 On the Aluminum Cluster Superatoms acting as Halogens and Alkaline-earth Metals, Bergeron, Dennis E et al., 2006 Beyond The Periodic Table, Computational Chemistry Portal, 2006 Expanding the periodic table? The Scientist, 2005 Clusters of Aluminum Atoms Found to Have Properties of Other Elements Reveal a New Form of Chemistry , innovations report, 2005. Have a picture of Al14. Clusters of Aluminum Atoms Found to Have Properties of Other Elements Reveal a New Form of Chemistry, Penn State, Eberly College of Science, 2005 Research Reveals Halogen Characteristics innovations report, 2004. Have pictures of Al13. 原子物理学 簇合物化学也可以观察到与原子轨道相似的超原子态 Li(HF)3Li = (HF)3 就像原子核 VSi16F = 具有离子键 13个铂原子的原子簇 2000个铷原子的原子簇 配体金属团簇超原子 核心是金属超原子的有机配体金属团簇。Y,d轨道电子贡献了超原子磁矩,ZrO和WC分别是金属Ni、

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